5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 1 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 1 - Product and Company Identification ****** Supplier: Axalta Coating Systems Canada Company 408 Fairall Street Ajax, ON, L1S 1R6 Manufacturer: Axalta Coating Systems, LLC 1007 Market Street, D-13111 Wilmington, DE, 19898 Telephone: Product Information: (800) 387-2122 Medical Emergency (24 hours): (855) 274-5698 Transportation Emergency (24 hours): (613) 996-6666(CANUTEC) PRODUCT IDENTIFIER: METAL CONDITIONER PRODUCT CODE: 5717S 061128 Prepared by: Regulatory Affairs Chemical Family: Not Available Copyright (c) 2013 Axalta Coating Systems Canada Company. All rights reserved. Copies may be made only for those using Axalta Coating Systems products. ****** SECTION 2 - Composition, Information on Ingredients ****** CAS # Ingredient (%) Exposure Limits** ------------ ------------------- ------------- ---------------- 7664-38-2 PHOSPHORIC ACID 30- 60 A 3.0 mg/m3 15 min STEL A 1.0 mg/m3 O 1.0 mg/m3 D 3.0 mg/m3 15 min TWA D 1.0 mg/m3 8 & 12 hour TWA 111-76-2 ETHYLENE GLYCOL MONOBUTY- 10- 30 A 20.0 ppm L ETHER O 50.0 ppm Skin D 20.0 ppm 8 & 12 hour TWA 7732-18-5 WATER 40- 70 A None O None ** A = ACGIH, O = OSHA, D = Dupont, TWAEV = Ontario, S = Supplier D=Dupont Results obtained from E.I. duPont de Nemours and Company
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 2 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 2 - Composition, Information on Ingredients ****** Cont'd (For additional definition of terms, see section 16) Limits are 8-hour TWA unless otherwise specified. ****** SECTION 3 - Hazards Information ****** Emergency Overview: WARNING! COMBUSTIBLE LIQUID AND VAPOR. VAPORS AND SPRAY MIST HARMFUL IF INHALED. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS DIZZINESS, HEADACHE, OR NAUSEA. MAY CAUSE NOSE, THROAT, EYE AND SKIN IRRITATION. CAN BE ABSORBED THROUGH THE SKIN. Potential Health Effects: Inhalation: May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Ingestion: May result in gastrointestinal distress. Skin or eye contact: May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Other Potential Health Effects in addition to those listed above: PHOSPHORIC ACID Ingestion may cause any of the following: burns to mouth and stomach Inhalation of vapor may cause: burns to respiratory system Skin or eye contact may cause any of the following: burns ETHYLENE GLYCOL MONOBUTYL ETHER Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: bone marrow central nervous system eyes gastrointestinal system kidneys liver respiratory system skin May cause injury to the kidneys, liver, blood and/or bone marrow. Repeated overexposure may result in damage to the blood. Eye contact may cause corneal injury. If absorbed through the skin, may be: harmful ****** SECTION 4 - First Aid Measures ****** First Aid Procedures: Inhalation: If affected by inhalation of vapor or spray mist, move to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing difficulty persists, or occurs later,
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 3 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 4 - First Aid Measures ****** Cont'd consult a physician. Ingestion: In the unlikely event of ingestion, DO NOT induce vomiting. Call a physician immediately and have names of ingredients available. Skin or eye: In case of contact, immediately flush with plenty of water for at least 15 minutes; call a physician. In case of skin contact, wash thoroughly with soap and water. If irritation occurs, contact a physician. ****** SECTION 5 - Firefighting Measures ****** Flash Point (Method) Between 61 to 93 deg C Closed Cup Approx. flammable limits LFL 1.1 % UFL 10.6 % Auto ignition temperature 224.0 Deg C Hazardous Combustion Products: CO, C02, smoke, and oxides of any heavy metals that are reported in "Composition, Information on Ingredients" section. Extinguishing media: Universal aqueous film-forming foam, carbon dioxide, dry chemical. Special fire fighting procedures: Full protective equipment, including self-contained breathing apparatus, is recommended. Water from fog nozzles may be used to prevent pressure build-up. Fire & explosion hazards: Combustible liquid. When heated above the flashpoint, emits vapors which, when mixed with air, will burn if an ignition source is present. Fine mist or sprays could ignite at temperatures below the flashpoint. ****** SECTION 6 - Accidental Release Measures ****** Procedures for cleaning up spills or leaks: Ventilate area. If heated above the flashpoint, remove sources of ignition. Prevent skin and eye contact and breathing of vapor. Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly. ****** SECTION 7 - Handling and Storage ****** Precautions to be taken in handling and storing: Observe label precautions. Keep away from heat, sparks and flame, static discharge and other sources of ignition. When heated above its flash point, this must be handled as if it were a flammable liquid. Close container after each use. Do not transfer contents to bottles or unlabeled containers. Wash thoroughly after handling and before
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 4 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 7 - Handling and Storage ****** Cont'd eating or smoking. OSHA/NFPA Storage Classification: IIIA Other precautions: If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation , and gloves. ****** SECTION 8 - Exposure Controls or Personal Protection ****** Engineering controls and work practices: Ventilation: Provide sufficient ventilation in volume and pattern to keep contaminants below applicable exposure limits. Personal Protective Equipment: Recommended PPE: Respiratory: Do not breathe vapours or mists. Wear an appropriate, properly fitted NIOSH approved respirator during application and until all vapours and spray mists are exhausted unless air monitoring demonstrates vapour/mist levels are below applicable limits. If respirators are required, use a properly fitted air-purifying respirator with organic vapour cartridges (NIOSH approved TC-23C) and particulate filter (NIOSH TC-84A). In confined spaces, or in situations where continuous spray operations are typical, or if proper air-purifying respirator fit is not possible, wear a positive pressure, supplied-air respirator (NIOSH TC-19C). In all cases, follow respirator manufacturer's directions for respirator use. Protective clothing: Neoprene gloves and coveralls are recommended. Eye protection: Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash guard or side shields. ****** SECTION 9 - Physical and Chemical Properties ****** Evaporation Rate Slower than Ether Vapor Pressure of principal solvent 23.60 mm @ 20 Deg C Solubility of solvent in water NIL Vapour density (principal solvent) 0.60 Approx. Boiling range (deg C) 100 - 265 DEG (C) Approx. Freezing range (deg C) -75 DEG (C) Gallon weight (lbs/US gal) 9.65 Specific gravity 1.16 Percent volatile by volume 80.49 Percent volatile by weight 67.70 Percent solids by volume 19.51 Percent solids by weight 32.30
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 5 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 9 - Physical and Chemical Properties ****** Cont'd Physical state Liquid pH (waterborne systems only) Not Applicable VOC* less exempt (g/l) 453.1 VOC* as packaged (g/l) 177.7 * VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of manufacture. ****** SECTION 10 - Stability and Reactivity ****** Stability: Stable Incompatibility (materials to avoid): None reasonably foreseeable Hazardous decomposition products: CO, C02, smoke, and oxides of any heavy metals that are reported in "Composition, Information on Ingredients" section. Hazardous polymerization: Will not occur. Sensitivity to static discharge: If heated above the flash point, solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product. Sensitivity to mechanical impact: None Known ****** SECTION 11 - Toxicological Information ****** PHOSPHORIC ACID Oral LD50 1530 mg/kg Rat SUPPLIER MSDS Dermal LD50 2470 mg/kg Rabbit SUPPLIER MSDS ETHYLENE GLYCOL MONOBUTYL ETHER Oral LD50 1746 mg/kg Rat SUPPLIER MSDS Dermal LD50 435 mg/kg Rabbit SUPPLIER MSDS Inhalation LC50 691 ppm 1 h Guinea Pig SUPPLIER MSDS For all other ingredients, no information is available. Key: RTECHS - Registry of Toxic Effects of Chemical Substances CCOHS - Canadian Center for Occupational Health and Safety Patty's - Patty's Industrial Hygiene and Toxicology, 3rd Edition
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 6 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013
****** SECTION 12 - Ecological Information ******
PHOSPHORIC ACID 138 mg/l 96 h FISH
ETHYLENE GLYCOL MONOBUTYL ETHER 1490 mg/l 4 days Bluegill Sunfish FISH 2137 mg/l 4 days Fathead Minnow FISH 1850 mg/l 1 days Daphnia INVERTEBRATES
****** SECTION 13 - Disposal Considerations ******
Provincial Waste Classification: Check appropriate provincial and local waste disposal regulations for proper classifications.
Waste disposal method: Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with Federal, State, Provincial, and local requirements. Use only approved waste management contractors. Do not incinerate in closed containers.
****** SECTION 14 - Transportation Information ******
TDG Shipping Name: PHOSPHORIC ACID, SOLUTION
Hazard Class: 8UN/NA# 1805Packing Group: III
****** SECTION 15 - Regulatory Information ******
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
TSCA Status: In compliance with TSCA Inventory requirements for commercial purposes. DSL Status: All components of the mixture are listed on the DSL. OCI: One or more components of the mixture are not listed on the Ontario Inventory. WHMIS Classification:
Class B Division 3 Class D Division 1 Subdivision A Class D Division 2 Subdivision B 60 Class E
WHMIS symbols: Flame Skull and Crossbones Corrosive
Photochemical Reactivity: Non-photochemically reactive
5717S AXALTA MATERIAL SAFETY DATA SHEET Page: 7 AXALTA COATING SYSTEMS CANADA COMPANY 05/05/2013 ****** SECTION 15 - Regulatory Information ****** Cont'd Other Regulatory Information: EPCRA CERCLA CAS # Ingredient 302 TPQ/RQ 311/312 313 RQ(lbs) HAP ------------ ------------------------- --- ------ ------- --- ------- --- 7664-38-2 PHOSPHORIC ACID N NR N N 5000 N 111-76-2 ETHYLENE GLYCOL MONOBUTY- N NR A,C,F Y NR N L ETHER 7732-18-5 WATER N NR N N NR N Key: EPCRA: Emergency Planning and Community Right-to-Know Act (aka Title III, SARA) 302: Extremely hazardous substances 311/312 Categories: F = Fire Hazard A = Acute Hazard R = Reactivity Hazard C = Chronic Hazard P = Pressure Related Hazard 313 Information: Section 313 Supplier Notification - The chemicals listed above with a 'Y' in the 313 column are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know act of 1986 and of 40 CFR 372. CERCLA: Comprehensive Emergency Response, Compensation and Liability Act of 1980. HAP = Listed as a Clean Air Act Hazardous Air Pollutant TPQ = Threshold planning quantity RQ = Reportable quantity NA = not available NR = not regulated ****** SECTION 16 - Additional Information ****** HMIS Rating: H: 3 F: 2 R: 1 Glossary of Terms: ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer NTP - National Toxicology Program OSHA - Occupational Safety and Health Administration STEL - Short term exposure limit TWA - Time-weighted average PNOR - Particles not otherwise regulated PNOC - Particles not otherwise classified Notice from Axalta Coating Systems The information on this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Approved by: Technical Manager
